Benzene, [(chloromethoxy)methyl]-
Benzylchloromethyl ether
CAS: 3587-60-8
Molecular Formula: C8H9ClO
Benzene, [(chloromethoxy)methyl]- - Names and Identifiers
| Name | Benzylchloromethyl ether |
| Synonyms | BOM-Cl Benzyloxymethyl chloride Benzylchloromethyl ether BENZYLOXYMETHYL CHLORIDE BENZYL CHLOROMETHYL ETHER Benzyl chloromethyl ether Chloromethyl benzyl ether (CHLOROMETHOXYMETHYL)BENZENE Benzene, [(chloromethoxy)methyl]- 1,1'-[oxybis(2-chloroethane-2,1-diyl)]dibenzene (Chloromethoxymethyl)benzene, Benzyloxymethyl chloride |
| CAS | 3587-60-8 |
| EINECS | 628-927-1 |
| InChI | InChI=1/C16H16Cl2O/c17-15(11-13-7-3-1-4-8-13)19-16(18)12-14-9-5-2-6-10-14/h1-10,15-16H,11-12H2 |
| InChIKey | LADPCMZCENPFGV-UHFFFAOYSA-N |
Benzene, [(chloromethoxy)methyl]- - Physico-chemical Properties
| Molecular Formula | C8H9ClO |
| Molar Mass | 156.61 |
| Density | 1.126 g/mL at 20 °C (lit.) |
| Boling Point | 102 °C/14 mmHg (lit.) |
| Flash Point | 91 °C |
| Water Solubility | Soluble in water [2.7 g/L (25 C)] |
| Vapor Presure | 0mmHg at 25°C |
| Appearance | Liquid |
| Color | Clear colorless to pale yellow |
| BRN | 1364034 |
| Storage Condition | 2-8°C |
| Refractive Index | n20/D 1.527 |
| Physical and Chemical Properties | Density 1.13 Boiling point 102°C (14 mmHg) Refractive index 1.5260 Flash point 91°C |
Benzene, [(chloromethoxy)methyl]- - Risk and Safety
| Risk Codes | R45 - May cause cancer R22 - Harmful if swallowed R23 - Toxic by inhalation R37/38 - Irritating to respiratory system and skin. R41 - Risk of serious damage to eyes R48/22 - Harmful danger of serious damage to health by prolonged exposure if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R50 - Very Toxic to aquatic organisms R43 - May cause sensitization by skin contact |
| Safety Description | S53 - Avoid exposure - obtain special instructions before use. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39 - Wear eye / face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S36 - Wear suitable protective clothing. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | UN 2810 6.1/PG 3 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 19-21 |
| HS Code | 29093090 |
| Hazard Class | 6.1(b) |
| Packing Group | III |
Benzene, [(chloromethoxy)methyl]- - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| use | organic synthesis intermediate. Used as an acid protecting group; introduce benzoic acid group and hydroxymethyl group |
| production method | is obtained by reacting benzyl alcohol, formaldehyde and hydrogen chloride together. First mix benzyl alcohol and formaldehyde solution, cool to 5 ℃, pass in hydrogen chloride to saturate the reaction liquid, and then continue to pass in hydrogen chloride at 10 ℃. The reactants are layered, the upper solution is dried with anhydrous calcium chloride, and the hydrogen chloride is removed under reduced pressure. Then distillation under reduced pressure, collect 96-99 degrees C (1.47kPa) fraction, to obtain the product. |
Last Update：2024-04-10 22:29:15
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